Department of Chemistry
Office:617-627-3124 Cell:781-526-4137 Fax:617-627-3443
Research Homepage: http://planetary.chem.tufts.edu/
Professor of Chemistry, Department of Chemistry, Tufts University
Visiting Professor, Department of Earth Science & Engr, Imperial College London, UK
Postdoctoral Fellow, 1987-88, Harvard University, Cambridge, MA
The discovery of perchlorate on Mars led the group to investigate the same possibility in the Antarctic Dry Valleys. The study provided the first unambiguous discovery and clear evidence of the ubiquitous natural formation of perchlorate on Earth, with accumulation in arid environments and global atmospheric production. The discovery also suggests that the perchlorate reducing bacteria and arachea may be a remnant of a significant pre-oxygen Earth perchlorate ecosystem.
In addition to the current investigations exploring Mars' geochemistry and its potential for supporting past or present microbial life in surface or subsurface environments, their research (funded by NASA and NSF) also includes understanding the geochemical and environmental history as recorded by the chemistry of planetary surface materials, and the geobiochemistry in extreme environments on Earth in places such as the Antarctic Dry Valleys, Death Valley, and mid-Atlantic deep-ocean thermal vents. They are also interested in applying similar techniques to investigate the surface and sub-glacial oceans on other planetary bodies such as Jupiter's moon, Europa. The group's research in astrobiology is focused on exploring concepts and analytical techniques for unambiguous detection of microbial life in extraterrestrial settings, and the survivability of organics on Mars' surface.
Selected Recent Publications
Identification of the Perchlorate Parent Salts at the Phoenix Mars Landing Site and Possible Implications",
Evidence of Martian Perchlorate, Chlorate, and Nitrate in Mars Meteorite EETA79001: Implications for Oxidants and Organics, S. P. Kounaves, B. L. Carrier, G. D. O'Neil, S. T. Stroble, and M. W. Clair, Icarus, 2014, 229, 206-213. doi:10.1016/j.icarus.2013.11.012
Electrochemistry of Aqueous Colloidal Graphene Oxide on Pt Electrodes, G. D. O'Neil, A.W. Weber, R. Buiculescu, N. A. Chaniotakis, and S. P. Kounaves, Langmuir, 2014, 30, 9599-9606. doi:10.1021/la502053m
Comparison of the Phoenix Mars Lander Wet Chemistry Laboratory Soil Analyses with Antarctic Dry Valley Soils, Mars Meteorite EETA79001 Sawdust, and a Mars Simulant, S. T. Stroble, K. M. McElhoney, and
An Electrochemically Based Total Organic Carbon Analyzer for Planetary and Terrestrial On-Site Applications, S. T. Stroble and S. P. Kounaves, Anal. Chem., 2012, 84, 6271–6276. doi:10.1021/ac301704m
Effects of Extreme Cold and Aridity on Soils and Habitability: McMurdo Dry Valleys as an Analog for the Mars Phoenix Landing Site, L. K. Tamppari, R. M. Anderson, P. D. Archer Jr., S. Douglas, S. P. Kounaves, C. P. McKay, D. W. Ming, Q. Moore, J. E. Quinn, P. H. Smith, S. Stroble, A. P. Zent, Antarctic Science, 2012, 24, 211-228. doi:10.1017/S0954102011000800
The Oxidation-Reduction Potential of Aqueous Soil Solutions at the Mars Phoenix Landing Site, R. C. Quinn, J. D. Chittenden, S. P. Kounaves, and M. H. Hecht, Geophys. Res. Lett., 2011, 38, L14202. doi:10.1029/2011GL047671
Soluble Sulfate in the Martian Soil at the Phoenix Landing Site, S. P. Kounaves, M. H. Hecht, J. Kapit, R. C. Quinn, D. C. Catling, B. C. Clark, D. W. Ming, K. Gospodinova, P. Hredzak, K. McElhoney, and J. Shusterman, Geophys. Res. Lett., 2010, 37, L09201. doi:10.1029/2010GL042613
Discovery of Natural Perchlorate in the Antarctic
Dry Valleys and its Global Implications,
Wet Chemistry Experiments on the 2007 Phoenix Mars
Scout Lander: Data Analysis and Results
Detection of Perchlorate and the Soluble Chemistry
of Martian Soil at the Phoenix Lander Site, M. H. Hecht,
H2O at the Phoenix Landing Site, P. H. Smith, L.
K. Tamppari, R. E. Arvidson, D. Bass, D. Blaney, W. V. Boynton, A. Carswell, D.
C. Catling, B. C. Clark, T. Duck, E. DeJong, D. Fisher, W. Goetz, H. P.
Gunnlaugsson, M. H. Hecht, V. Hipkin, J. Hoffman, S. F. Hviid, H. U. Keller, S.
P. Kounaves, et al.,
Complete list of publications can be found HERE.
Selected Media & E/PO Links
- AAAS Annual Meeting News "Perchlorate on Mars" February 2013
- The Analytical Scientist "Quantitative Analysis and the Essence of Doing Good Science" January 2013
- NECN TV "Curiosity Rover Lands on Mars" August 2012
- WGBH 7 One Guest Interview May 2009
- NOVA ScienceNOW "Phoenix Lander Wet Chemistry with PBS/Tyson" July 2008