Department of Chemistry
Tel: 617-627-2443 Fax: 617-627-3443
Senior Lecturer in Chemistry
Ph.D., 1997, Institute of Physical Chemistry,
Ukrainian Academy of Sciences, Kiev
Selected Recent Publications
"Proton-directed redox control of O-O bond activation by heme hydroperoxidase models", J. D. Soper, S. V. Kryatov, E. V. Rybak-Akimova, and D. G. Nocera, J. Am. Chem. Soc., 2007, 129, 5069-5075.
"Diiron(III) oxo-bridged complexes with BPMEN and additional monodentate or bidentate ligands: Synthesis and reactivity in olefin epoxidation with H2O2", S. Taktak, S. V. Kryatov, T. E. Haas, and E. V. Rybak-Akimova, J. Mol. Catal. A, 2006, 259, 24-34.
"Kinetics and Mechanisms of Formation and Reactivity of Non-heme Iron Oxygen Intermediates', S. V. Kryatov, E. V. Rybak-Akimova, and S. Schindler, Chem. Rev., 2005, 105, 2175-2226
"Dioxygen Binding to Complexes with FeII2(m-OH)2 Cores: Steric Control of Activation Barriers and O2-Adduct Formation", S. V. Kryatov, S. Taktak, I. V. Korendovych, E. V. Rybak-Akimova, J. Kaizer, S. Torelli, X. Shan, S. Mandal, V. L. MacMurdo, A. Mairata-Payeras, and L. Que, Inorg. Chem., 2005, 44, 85-99.
"Mechanistic Studies on the Formation and Reactivity of Dioxygen Adducts of Diiron Complexes Supported by Sterically Hindered Carboxylates', S. V. Kryatov, F. A. Chavez, A. M. Reynolds, E. V. Rybak-Akimova, L. Que, and W. B. Tolman, Inorg. Chem., 2004, 43, 2141-2150.