- Department of Chemistry
Pearson Chemical Laboratory
PhD, Institute of Physical Chemistry, Ukrainian Academy of Sciences, Kiev, 1997
BS/MS, Kiev State University, Ukraine, 1991
Kinetics and mechanism of oxygen and hydrogen peroxide activation by metal complexes.
Selected Publications and Presentations
"Kinetic Studies on the Oxoiron(IV) Complex with Tetradentate Aminopyridine Ligand PDP*: Restoration of Catalytic Activity by Reduction with H2O2", M. C. Piquette, S. V. Kryatov, and E. V. Rybak-Akimova, Inorg. Chem., 2019, 58, 13382-13393.
"Kinetic Insights into the Reactivity of the Intermediates Generated from Hydrogen Peroxide and Diiron(III) Complex with Tris(picolyl)amine", X. Sun, S. V. Kryatov, and E. V. Rybak-Akimova, Dalton Trans., 2013, 42, 4427-4435.
"Dioxygen activation at non-heme iron: Insights from rapid kinetic studies", I. V. Korendovych, S. V. Kryatov, and E. V. Rybak-Akimova, Acc. Chem. Res., 2007, 40, 510-521.
"Proton-directed redox control of O-O bond activation by heme hydroperoxidase models", J. D. Soper, S. V. Kryatov, E. V. Rybak-Akimova, and D. G. Nocera, J. Am. Chem. Soc., 2007, 129, 5069-5075.
"Diiron(III) oxo-bridged complexes with BPMEN and additional monodentate or bidentate ligands: Synthesis and reactivity in olefin epoxidation with H2O2", S. Taktak, S. V. Kryatov, T. E. Haas, and E. V. Rybak-Akimova, J. Mol. Catal. A, 2006, 259, 24-34.
"Kinetics and Mechanisms of Formation and Reactivity of Non-heme Iron Oxygen Intermediates', S. V. Kryatov, E. V. Rybak-Akimova, and S. Schindler, Chem. Rev., 2005, 105, 2175-2226
Introductory and organic chemistry courses: Chem 1, Chem 2, Chem 51-54